The Charge of the Ultra - Capacitors Continued
By Joel Schindall
First Published November 2007
Photo: Riccardo Signorelli/MIT
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ELECTRIC SHAG: A cross section of an electrode made with
carbon nanotubes.
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Small-cell ultracapacitors can be used in cars for
purposes other than in the drivetrain. They can be
integrated into air-conditioning, electric power
steering, power locks, and window systems—components
that demand high peak currents, which typically require
large-diameter wiring. The need is intermittent, and the
average power is low, so having ultracapacitors provide
the high current at strategic points would permit
thinner wiring to be installed. With the high price of
copper these days, such changes can shave an appreciable
amount from the cost of a vehicle.
Safety is another motivation. Suppose a car has
electrically actuated brakes or door locks and the
wiring harness fails because of a defect or an accident.
A local ultracapacitor can still provide power for a few
precious seconds or minutes.
Such devices are by no means limited to vehicles.
Society is in the midst of an energy crisis, and many
sources of green energy would benefit from regenerative
energy storage. Electric power grids could be 10 percent
more efficient if there could be simple, inexpensive
ways to store energy locally at the point of use. And if
renewable energy is ever to displace fossil fuels,
engineers will need to devise better ways to store wind
power when the wind is not blowing and solar power when
the sun is not shining.
My colleagues and I are not the only ones researching
ultracapacitor technology, of course. All the existing
ultracapacitor manufacturers—including Maxwell
Technologies, NessCap, Panasonic, Nippon Chemi-Con, and
Power Systems Co.—are working on improved activated
carbons or devices where one electrode functions as a
battery and the other as an ultracapacitor. The Japanese
government has provided $25 million for nanotube
research, money that has supported a promising joint
effort between Nippon Chemi‑Con and AIST National Lab to
explore nanotube-based techniques. Investigators at
Rensselaer Polytechnic Institute, in Troy, N.Y.,
recently announced, in the Proceedings of the National
Academy of Sciences of the United States of America, an
exciting combined battery-nanotube ultracapacitor fabric
to store electrical energy.
And nanotube forests are not the only way to provide
increased porosity. Power Systems, in Japan, for
example, has been getting good results with a type of
graphene structure that it calls a “nanogate.”
There's a slightly different approach to modified
capacitors that has been generating a lot of buzz
lately, developed by a start-up called EEStor, in Cedar
Park, Texas. EEStor has focused on improving the
dielectric, rather than the capacitor's plates. Its
design uses barium titanate, which has a high dielectric
constant. High-dielectric-constant substances allow for
high-value capacitors that are still small in size. The
downside is that such materials generally are unable to
withstand electrostatic fields of the same intensity as
low-dielectric-constant substances such as air. EEStor
claims that the capacitors can operate at extremely high
voltages, on the order of several thousand volts,
leading to very high storage capacities. One concern is
that high voltages can cause a dielectric to break down
irreversibly in the presence of even slight
imperfections in the material. Only time will tell how
its design fares.
Improving substantially on the means to store
electrical energy would be a welcome development, and
high-density capacitive storage is one promising avenue
of research. Although batteries and capacitors are old
inventions, our particular technique could not have been
pursued until recently. Just as semiconductor designers
have created smaller and smaller transistors, so have
engineers in other areas learned to manipulate objects
with ever-more-minuscule dimensions. The ability to
sculpt materials at the atomic level is new and
evolving. Engineers can use these new techniques to
achieve novel properties and, in the case of my lab's
research, to move toward a nanoengineered carbon that
might usher in the next generation of energy storage.
About the Author
JOEL SCHINDALL spent 35 years working in the
telecommunications and satellite industries before
joining the faculty of MIT, where he is now
associate director of the Laboratory for
Electromagnetic and Electronic Systems.
To Probe Further
For an overview of ultracapacitors and their
applications, as well as a number of free technical
papers (after registration), visit http://www.maxwell.com/ultracapacitors/technical-support/white_papers.asp.
The National Renewable Energy Laboratory, in
Golden, Colo., surveys its energy storage research at
http://www.nrel.gov/vehiclesandfuels/energystorage/ultracapacitors.html.